Eur. Phys. J. Appl. Phys.
Volume 98, 2023
Special Issue on ‘Amorphous alloys and multiscale materials: Fundamental aspects and Energy applications’, edited by Zhao Zhankui, Wang Hongli and Tai Cheuk-Wai
|Number of page(s)||8|
|Section||Physics of Energy Transfer, Conversion and Storage|
|Published online||17 April 2023|
Mg-doped NiCoP microflower grown on Ni foam for high-capacity supercapacitor electrode
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, P.R. Chin
* e-mail: firstname.lastname@example.org, email@example.com
Received in final form: 27 February 2023
Accepted: 8 March 2023
Published online: 17 April 2023
In this work, a binder-free electrode Mg-doped NiCoP/Ni foam (MNCP-x/NF) was prepared via hydrothermal and phosphorization process, in which echinoid microflower-like MNCP-x was densely loaded on the NF skeleton. By regulating the Mg2+ doping amount, remarkable enhancements in the morphology, mass-loading of MNCP, electrode conductivity and overall electrochemical capacitive properties of MNCP-x/NF have been achieved. Particularly, moderate doped MNCP-0.5/NF exhibits the best energy storage performances with a superior specific capacity (4461 mC cm−2 @ 2 mA cm−2), acceptable rate capability (retaining 50.1% @ 50 mA cm−2), and striking cyclability (retaining 83% over 5000 cycles). Moreover, a solid-state asymmetric supercapacitor constructed with MNCP-0.5/NF as cathode, graphene hydrogel/NF (GH/NF) as anode, PVA/KOH gel as electrolyte, outputs the notable energy density of 39.8 Wh kg−1 (1.8 mWh cm−3) and power density of 16674 W kg−1 (750 mW cm−3), companied by a superior cyclability (retaining 87% over 5000 cycles).
© EDP Sciences, 2023
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