Structural and electrical properties of thermally evaporated cobalt phthalocyanine (CoPc) thin films

¹ Physics department, faculty of girls, Jedda, Saudi Arabia Kingdom
² Physics Department, Faculty of Education, Ain Shams University, Cairo, Egypt

Corresponding author: amall56@yahoo.com

Received: 31 May 2006
Revised: 22 August 2006
Accepted: 28 August 2006
Published online: 15 November 2006

Abstract

Thin films of CoPc of various thickness have been deposited onto glass substrates using thermal evaporation technique at room temperature. The dark electrical resistivity measurements were carried out at different temperature range (298–423 K). An estimation of mean free path () of charge carriers in CoPc thin films and bulk resistivity, was attempted. Measurements of thermoelectric power confirm that CoPc thin films behave as p-type semiconductors. The ac conductivity (σ_ac) has been investigated in the frequency range (10²–10⁶ Hz) and temperature range (298–407 K). σ_ac is found to be proportional to ω^s where s ≈ 0.879 which is frequency and temperature independence. The ac conductivity interpreted by the correlated barrier hopping (CBH) model with centers of intimate valence alternation pairs type with a maximum barrier height, W_M ≈ 1.594 eV.