Issue |
Eur. Phys. J. Appl. Phys.
Volume 36, Number 2, November 2006
|
|
---|---|---|
Page(s) | 141 - 147 | |
Section | Characterization of Materials: Imaging, Microscopy and Spectroscopy | |
DOI | https://doi.org/10.1051/epjap:2006108 | |
Published online | 11 October 2006 |
https://doi.org/10.1051/epjap:2006108
AC response of Bi-modified Pb0.92La0.08(Zr0.65Ti0.35)0.98O3 ceramics
1
Department of Physics and Meteorology, Indian Institute of Technology, Kharagpur – 721302, India
2
Department of Aerospace Engineering, Indian Institute of Technology, Kharagpur – 721302, India
Corresponding author: dutta_som@yahoo.co.in
Received:
28
October
2005
Revised:
1
June
2006
Accepted:
21
June
2006
Published online:
11
October
2006
Polycrystalline electroceramics have been prepared by varying modifier to former (Bi/La) ratios () according to the complex formula
Pb0.92[La
Biz] 0.08[Zr0.65Ti0.35] 0.98O3 (PLBZT), where z = 0.0, 0.3, 0.6.
The electrical properties of PLBZT compounds were studied using the ac
impedance spectroscopy technique over a wide range of temperature
(30–500 °C) in the frequency range of 100 Hz–1 MHz.
Nyquist plots recorded at different temperatures show a decrease in the bulk
resistance (Rb) with rise in temperature for PLZT material (z = 0.0)
i.e., NTCR behavior like semiconductors. The Nyquist plots also indicates
that the bulk resistance of the material has been observed to be
concentration dependent and decreased in two order of magnitude with higher
Bi-addition in PLZT matrix. Bismuth (Bi) substitution at the lanthanum (La)
position not only resulted in lowering of the electrical resistance with its
higher concentration but also has changed the NTCR behavior of PLZT (z = 0.0) to PTCR (positive temperature coefficient of resistance) for PLBZT.
Electrical property studied by complex impedance spectroscopic method also
indicates the evidence of (i) single electrical relaxation attributed to the
presence of bulk contribution to the electrical properties, (ii) presence of
temperature dependent electrical relaxation phenomenon and (i) diminution in
the barrier to the mobility of charge carrier on Bi-substitution.
PACS: 77.84.Dy – Niobates, titanates, tantalates, PZT ceramics, etc. / 77.80.Bh – Phase transitions and Curie point / 77.22.Ch – Permittivity (dielectric function) / 84.37.+q – Measurements in electric variables (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.)
© EDP Sciences, 2006
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