Table 1
Data for In, Ag, Al, Ag-In and Ag-Al (Wigner-Seitz radii (rs), surface energies (Es), LSPR wavelengths (λLSPR) and energies (ELSPR) of a sphere in a porous silica matrix (εm ≈ 2.17) in the dipolar approximation) and crystallographic properties of pure metals, Ag-In and Ag-Al alloys and oxides. All the corresponding references are indicated in the table. BCT, HCP, SC, FCC stand for body-centred tetragonal, hexagonal-closed packed, simple cubic, face-centred cubic lattices, respectively.
| In | Ag | Al | |
|---|---|---|---|
| r s ( Å ) 21 | 1.83 | 1.60 | 1.59 |
| E s (J.m-2) 22 | 0.700 | 1.24 | 1.14 |
| λLSPR (nm) in porous silica (dipolar approximation) | 226 | 398 | 193 |
| E LSPR (eV) | 5.48 | 3.12 | 6.42 |
| Crystallographic structure 23 | BCT a = 3.24 Å c = 4.95 Å |
FCC a = 4.09 Å |
FCC a = 4.05 Å |
| Alloys | Ag4In (FCC) 24, a = 4.14 Å
Ag3In (SC) 24, a = 4.13 Å ς-Ag7In3 (HCP) 24, (a, c) = (2.95 Å, 4.79 Å) Ag2In (SC) 25, a = 9.92 Å |
||
|
ζ-Ag2Al (HCP)
23
, (a, c) = (2.87 Å, 4.67 Å) μ-Ag3Al (SC) 23 , a = 6.93 Å |
|||
| Oxides | c-In2O3 (FCC) 26
h-In2O3 (HCP) 27 |
Ag2O (SC) 23 | α-Al2O3 (HCP) 23 |
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