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Eur. Phys. J. Appl. Phys. 24, 195-200 (2003)
DOI: 10.1051/epjap:2003067
Degradation kinetics of the spectral emission in polyfluorene light-emitting electro-chemical cells and diodes
T. Ouisse1, O. Stéphan1 and M. Armand21 Laboratoire de Spectrométrie Physique, Université Joseph Fourier, Grenoble 1 and CNRS UMR C5588, 140 rue de la physique, BP 87, 38042, Saint-Martin d'Hères Cedex, France
2 Laboratoire International sur les Matériaux Électroactifs, CNRS, UMR 2289, Université de Montréal, CP 6128, Montréal QC H3C 3J7, Canada
ouisse@spectro.ujf-grenoble.fr
(Received: 21 March 2003 / Received in final form: 4 July 2003 / Accepted: 10 July 2003 Published online: 16 September 2003 )
Abstract
We have studied the well known spectral shift of polyfluorene blue light emitters,
using either electrochemical cells or conventional organic light emitting diodes. From the
recording of the electroluminescence spectra as a function of "stress" time, we conclude that
the degradation mainly depends on the number of electrons which have passed through the
conducting polymer, rather than on the hole current magnitude or the dissipated power.
73.61.Ph - Polymers; organic compounds.
72.80.Le - Polymers; organic compounds (including organic semiconductors).
85.60.Jb - Light-emitting devices.
© EDP Sciences 2003
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